Synthesis and Photocatalytic Performance Evaluation of BaTiO3/ZnO/Cs3Bi2I9 Based Perovskite for Solar Cell Applications

Authors

  • Hala Allawi Kadhim Chemistry, University of Kufa, AlKufa, IRAQ.
  • Majida Hameed Khazaal Chemistry, University of Kufa, AlKufa, IRAQ.

DOI:

https://doi.org/10.22452/mjs.vol44no3.5

Keywords:

Perovskites, Solar cells, Nanoparticles, Thermal method, Barium titanate

Abstract

Due to the light absorption properties of perovskites, including halides, perovskite cells are considered an ideal energy system. This study aims to improve photoexcitation separation by introducing a material with a perovskite-like structure, such as Cs3Bi2I9, alone or with barium titanate nanoparticles as a second choice, while the third choice is to impregnate barium titanate (prepared by hydrothermal method) with ZnO to form  BaTiO3/ZnO, then mix it with  Cs3Bi2I9. All these choices are fabricated as a sandwich between the n-type and p-type collection. The produced layers, BaTiO3/ZnO /Cs3Bi2I9, were characterized using XRD, EDX, SEM, and UV-Vis spectroscopic analytical techniques. The results suggest that the band gap of the prepared layer was further decreased compared to the original material, Cs3Bi2I9. The performance test revealed a photo conversion efficiency (PCE) of 3.13% and a highest power of 3.15 MW, comparable to or higher than other studies. This suggests that this layer significantly reduces recombination phenomena and improves the cell's performance overall.

Downloads

Download data is not yet available.

References

Abd, A. N. (2023). Free-Lead Perovskite Materials , CsFeCl3 And Cs3Fe2Cl9 , In Solar Cell. ACE Journal of Advance Research In Physical Sciences, July. https://doi.org/10.59218/makacejarps.2023.12.19

Al-Marzouki, F. M., Al-Hartomy, O. A., & Shah, M. A. (2011). Preparation of copper oxide (CuO) nanoparticles and their bactericidal activity. International Journal of Manufacturing, Materials, and Mechanical Engineering, 1(4), 58–64. https://doi.org/10.4018/ijmmme.2011100104

Arjmand, F., Fatemi, S. J., Maghsoudi, S., & Naeimi, A. (2022). The first and cost effectivenano-biocomposite, zinc porphyrin/ CuO/reduced graphene oxide, based on Calotropis procera plant for perovskite solar cellas hole-transport layerunderambient conditions. Journal of Materials Research and Technology, 16, 1008–1020. https://doi.org/10.1016/j.jmrt.2021.12.012

Article, R. (2016). A Brief Review on Synthesis and Characterization of Copper Oxide Nanoparticles and its Applications. Journal of Bioelectronics and Nanotechnology, 1(1), 1–9. https://doi.org/10.13188/2475-224x.1000003

Bai, F., Hu, Y., Hu, Y., Qiu, T., Miao, X., & Zhang, S. (2018). he first and cost effectivenano-biocomposite, zinc porphyrin/ CuO/reduced graphene oxide, based on Calotropis procera plant for perovskite solar cellas hole. Solar Energy Materials and Solar Cells, 184(January), 15–21. https://doi.org/10.1016/j.solmat.2018.04.032

Basaleh, A. S., & Mohamed, R. M. (2020). Synthesis and characterization of Cu-BaTiO3 nanocomposite for atrazine remediation under visible-light radiation from wastewater. Journal of Materials Research and Technology, 9(5), 9550–9558. https://doi.org/10.1016/j.jmrt.2020.06.081

Dorris, S. E., & Kumarakrishnan, S. (1983). Zyxw Zyxwvuts. 94(December).

Gunerhan, H., Hepbasli, A., & Giresunlu, U. (2009). Environmental impacts from the solar energy systems. Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 31(2), 1131–1138. https://doi.org/10.1080/15567030701512733

Hamed, T. A., & Alshare, A. (2022). Environmental Impact of Solar and Wind energy-A Review. Journal of Sustainable Development of Energy, Water and Environment Systems, 10(2), 1–23. https://doi.org/10.13044/j.sdewes.d9.0387

Harbbi, K. H., & Jahil, S. S. (2017). Study the Lattice Distortion and Particle Size of One Phase of MnO by Using Fourier Analysis of X-ray Diffraction Lines. Advances in Physics Theories and Applications, 65(x), 6–22.

Jassim, G., Najim, M., & Salih, W. (2021). Preparation of Micro Barium Titanate Powder and Comparison with Nano Powder Properties. Journal of Applied Sciences and Nanotechnology, 1(4), 12–23. https://doi.org/10.53293/jasn.2021.3653.1033

Maison, W., Kleeberg, R., Heimann, R. B., & Phanichphant, S. (2003). Phase content, tetragonality, and crystallite size of nanoscaled barium titanate synthesized by the catecholate process: Effect of calcination temperature. Journal of the European Ceramic Society, 23(1), 127–132. https://doi.org/10.1016/S0955-2219(02)00071-7

Mehta, S. K., Kumar, S., Chaudhary, S., & Bhasin, K. K. (2009). Supplementary Material (ESI) for Nanoscale Supplementary data Nucleation and growth of surfactant passivated CdS and HgS NPs: Time dependent Absorption and Luminescence profiles. The Royal Society of Chemistry, c, 1–6.

Omar, A., & Abdullah, H. (2014). Electron transport analysis in zinc oxide-based dye-sensitized solar cells: A review. Renewable and Sustainable Energy Reviews, 31, 149–157. https://doi.org/10.1016/j.rser.2013.11.031

Park, B. W., Philippe, B., Zhang, X., Rensmo, H., Boschloo, G., & Johansson, E. M. J. (2015). B. W. Park, B. Philippe. Advanced Materials, 27(43), 6806–6813. https://doi.org/10.1002/adma.201501978

Pescoe, ©, & Ali, F. M. (n.d.). A Review on Solar Energy Potential And Future world.

Rabiei, M., Palevicius, A., Monshi, A., Nasiri, S., Vilkauskas, A., & Janusas, G. (2020). Comparing methods for calculating nano crystal size of natural hydroxyapatite using X-ray diffraction. Nanomaterials, 10(9), 1–21. https://doi.org/10.3390/nano10091627

Ray, A. K. (2007). Synthesis and Charactrization Of BaTiO3 Powder Prepared By Combustion Synthesis Process

Sengupta, L. C., Stowell, S., Ngo, E., Oday, M. E., & Lancto, R. (1995). Barium strontium titanate and nonferroelectric oxide ceramic composites for use in phased array antennas. Integrated Ferroelectrics, 8(1–2), 77–88. https://doi.org/10.1080/10584589508012302

Tanaka, H., Oku, T., & Ueoka, N. (2018). Structural stabilities of organic–inorganic perovskite crystals. Japanese Journal of Applied Physics, 57(8), 0–9. https://doi.org/10.7567/JJAP.57.08RE12

Tanaka, K., Takahashi, T., Ban, T., Kondo, T., Uchida, K., & Miura, N. (2003). Comparative study on the excitons in lead-halide-based perovskite-type crystals CH3NH3PbBr3 CH3NH 3PbI3. Solid State Communications, 127(9–10), 619–623. https://doi.org/10.1016/S0038-1098(03)00566-0

Tomaszewski, P. E. (1994). Crystal Structure and Phase Transitions in the A3B2X9 Family of Crystals. Physica Status Solidi (B), 181(1), 15–21. https://doi.org/10.1002/pssb.2221810102

viewcontent.cgi. (n.d.).

Wang, M., Wang, W., Ma, B., Shen, W., Liu, L., Cao, K., Chen, S., & Huang, W. (2021). Lead-Free Perovskite Materials for Solar Cells. In Nano-Micro Letters (Vol. 13, Issue 1). Springer Singapore. https://doi.org/10.1007/s40820-020-00578-z

Zhang, C., Li, X., Ding, L., Jin, C., & Tao, H. (2022). Effect of BaTiO3 powder as an additive in perovskite films on solar cells. RSC Advances, 12(13), 7950–7960. https://doi.org/10.1039/d1ra09374f

Zhang, Z., Li, X., Xia, X., Wang, Z., Huang, Z., Lei, B., & Gao, Y. (2017). High-Quality (CH3NH3)3Bi2I9 Film-Based Solar Cells: Pushing Efficiency up to 1.64%. Journal of Physical Chemistry Letters, 8(17), 4300–4307. https://doi.org/10.1021/acs.jpclett.7b01952

zou2012.pdf. (n.d.).

Published

30-09-2025

How to Cite

Allawi Kadhim, H., & Majida Hameed Khazaal. (2025). Synthesis and Photocatalytic Performance Evaluation of BaTiO3/ZnO/Cs3Bi2I9 Based Perovskite for Solar Cell Applications. Malaysian Journal of Science (MJS), 44(3), 50–55. https://doi.org/10.22452/mjs.vol44no3.5

Issue

Section

Original Articles